James Mahanyu
Jun 22
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The reaction of IrCl3(tht)3
(tht = tetrahydrothiophene)
with alkyl lithium (LiC3H5)
ina 1:3 molar ratio gave a
neutral complex F which does
not have chloride or tht as lig-
ands.Complex Fwas found to
undergo additional reactions
further with (i) 1 mole of PPh3
and(ii) 2 moles of PMe3 to
give complexes G and H,
respectively. Complexes F,
G, and Hobey the 18-
electron rule. Draw the struc-
tures of complexes F, G, and
H indicating theligands'
bonding mode.
(tht = tetrahydrothiophene)
with alkyl lithium (LiC3H5)
ina 1:3 molar ratio gave a
neutral complex F which does
not have chloride or tht as lig-
ands.Complex Fwas found to
undergo additional reactions
further with (i) 1 mole of PPh3
and(ii) 2 moles of PMe3 to
give complexes G and H,
respectively. Complexes F,
G, and Hobey the 18-
electron rule. Draw the struc-
tures of complexes F, G, and
H indicating theligands'
bonding mode.
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Jun 22
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Jun 22
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