> #chemistry , #thermodynamics , #physics > Explain why gases behave non-ideally.
Anonymous
Aug 28

Explain why gases behave non-ideally.

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ChatGPT
Aug 28
Gases behave non-ideally due to several factors that deviate from the assumptions of the ideal gas law. These factors include:

1. Intermolecular forces: In an ideal gas, it is assumed that there are no intermolecular forces between gas molecules. However, in reality, gas molecules do interact with each other through weak forces such as Van der Waals forces. These interactions can cause deviations from ideal behavior, especially at high pressures and low temperatures.

2. Molecular volume: In the ideal gas law, gas molecules are assumed to have zero volume. In reality, gas molecules do have a finite volume, which becomes significant at high pressures and low temperatures. This leads to deviations from ideal behavior, especially at high pressures.

3. Real gas behavior: At high pressures and low temperatures, gases can deviate significantly from ideal behavior due to the compressibility factor, which takes into account the deviations caused by intermolecular forces and molecular volume. This leads to non-ideal behavior in gases under these conditions.

4. Chemical reactions: In some cases, gases can undergo chemical reactions that can affect their behavior. For example, gases can react to form new compounds or change their composition, leading to deviations from ideal behavior.

Overall, gases behave non-ideally due to a combination of factors such as intermolecular forces, molecular volume, real gas behavior, and chemical reactions. These factors can cause deviations from the ideal gas law under certain conditions, leading to non-ideal behavior in gases.
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Google Gemini AI
Aug 28
Gases behave non-ideally when the assumptions made in the ideal gas law are not met. These assumptions are:

- The gas particles are point masses with no volume.
- The gas particles do not interact with each other.
- The gas particles are in constant random motion.

When these assumptions are not met, the gas will behave non-ideally. This can be due to a number of factors, including:

- High pressure: At high pressures, the gas particles are squeezed closer together and begin to interact with each other. This can cause the gas to deviate from ideal behavior.
- Low temperature: At low temperatures, the gas particles are moving more slowly and have less energy. This can cause them to clump together and form clusters, which can also cause non-ideal behavior.
- Presence of impurities: If the gas contains impurities, such as water vapor or other gases, these impurities can interact with the gas particles and cause non-ideal behavior.

Non-ideal behavior can be accounted for by using a more complex equation of state, such as the van der Waals equation. This equation takes into account the volume of the gas particles and the interactions between them.

The van der Waals equation is given by:

```
P = nRT/(V - nb) - a(n/V)^2
```

where:

- P is the pressure of the gas
- n is the number of moles of gas
- R is the ideal gas constant
- T is the temperature of the gas
- V is the volume of the gas
- a and b are constants that depend on the gas

The van der Waals equation can be used to predict the behavior of non-ideal gases over a wider range of pressures and temperatures than the ideal gas law.
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Anonymous
Aug 28
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