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Show that the thermodynamic work done in compressing a gas at a constant pressure is given by the product of that pressure and volume?
Show that the thermodynamic work done in compressing a gas at a constant pressure is given by the product of that pressure and volume?
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Mar 2
To show that the work done in compressing a gas at a constant pressure is given by the product of that pressure and volume, we can use the first law of thermodynamics, which states:
ΔU = Q - W
Where: ΔU = change in internal energy of the gas Q = heat added to the gas W = work done on the gas
Since the process is done at constant pressure, we can write the work done as:
W = -PΔV
Where: P = pressure ΔV = change in volume
Since the pressure is constant, we can rewrite the work done as:
W = -P(Vf - Vi)
Where: Vf = final volume Vi = initial volume
Substitute this expression for work done into the first law of thermodynamics:
ΔU = Q + P(Vf - Vi)
Since the process is adiabatic (no heat exchange), Q = 0:
ΔU = P(Vf - Vi)
Since the change in internal energy is given by the ideal gas law as:
ΔU = nCvΔT
Where: n = number of moles of gas Cv = molar specific heat at constant volume ΔT = change in temperature
We can equate the two expressions for ΔU:
nCvΔT = P(Vf - Vi)
Rearranging the equation, we get:
PΔV = nCvΔT
Since the ideal gas law states:
PV = nRT
We can rewrite the equation as:
PΔV = nRΔT
Therefore, the work done in compressing a gas at a constant pressure is given by the product of that pressure and volume.