Chemical Weathering
Water is the primary agent of chemical weathering, causing the breakdown of rocks through various chemical processes:
- Dissolution: Water dissolves minerals in rocks, particularly those containing soluble salts (e.g., halite, gypsum). As the water flows through the rock, it gradually dissolves and removes these minerals, leaving voids or cavities.
- Hydrolysis: Water molecules react with certain minerals, especially feldspars and hornblende, breaking down their chemical bonds. This process forms new minerals, often clay minerals, and releases ions into the water.
- Oxidation: Oxygen dissolved in water helps to oxidize iron-bearing minerals, such as pyrite. The oxidation process produces iron oxides and releases sulfuric acid, which further reacts with the rock.
- Carbonation: Carbon dioxide dissolved in rainwater forms carbonic acid (H2CO3). Carbonic acid reacts with carbonate minerals (e.g., calcite, dolomite), converting them into soluble bicarbonate ions, which are then carried away by water.
Physical Weathering
- Freezing and Thawing: When water seeps into cracks and fissures in rocks, it can freeze and expand. This expansion exerts pressure on the surrounding rock, causing it to break apart. As the ice melts, water can infiltrate further into the rock, repeating the process and gradually breaking down the rock.
- Exfoliation: As outer layers of rock are subjected to extreme temperature fluctuations, they expand and contract at different rates. This causes the surface layers to peel away from the main body of the rock, resulting in exfoliation sheets or domes. Water can penetrate into these cracks and accelerate the exfoliation process.
Mechanical Weathering
- Erosion: Moving water, such as rivers, streams, and waves, can physically erode rocks by carrying away particles of broken rock, creating channels and canyons.
- Abrasion: When rocks collide with each other or with sediment carried by water, they can grind away and smooth the surfaces of the rocks.