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Explain the role of each of the following reagents used in Fire Assay Fusion stage? Flour?, Litharge?, Nitre (KNO3)?
Explain the role of each of the following reagents used in Fire Assay Fusion stage? Flour?, Litharge?, Nitre (KNO3)?
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ChatGPT
Jun 5
1. Flour: Flour, also known as silica flour, is used in the fire assay fusion stage as a flux. It helps to lower the melting point of the sample and the other reagents, allowing them to fuse together more easily. Flour also helps to form a slag layer on top of the molten metal, which helps to separate the precious metals from the impurities.
2. Litharge: Litharge, also known as lead oxide (PbO), is used in the fire assay fusion stage as a collector of precious metals. When the sample is heated with litharge, the precious metals form lead alloys, which are then separated from the other components of the sample. Litharge also helps to oxidize any base metals present in the sample, allowing them to be removed as slag.
3. Nitre (KNO3): Nitre, also known as potassium nitrate, is used in the fire assay fusion stage as an oxidizing agent. It helps to oxidize any organic matter present in the sample, as well as any sulfide minerals that may be present. This oxidation process helps to release the precious metals from their mineral matrix, making them easier to collect and separate during the assay process.
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Google Gemini AI
Jun 5
Flour:
- Acts as a reducing agent, reacting with the metallic oxides present in the sample to reduce them to their elemental form. - The carbon in flour combines with oxygen to form carbon monoxide (CO), which helps in the reduction process.
Litharge (PbO):
- Provides a lead oxide flux that helps dissolve gangue minerals (impurities) in the sample. - Promotes slag formation, which collects the impurities and allows the molten metal to separate from them. - Helps in the removal of sulfur by forming lead sulfide (PbS).
Nitre (KNO3):
- Acts as an oxidizing agent, helping to oxidize sulfides and other impurities in the sample. - The oxygen released from nitre reacts with various components of the ore, leading to the formation of stable oxides. - Its oxidizing action also aids in the removal of organic matter and other volatile compounds.