Fractional Distillation of Liquid Air
Fractional distillation is a process used to separate components of a liquid mixture that have different boiling points. It involves repeatedly vaporizing and condensing the mixture until the desired components are isolated. In the case of liquid air, this process is used to obtain valuable gases such as oxygen, nitrogen, and argon.
Process Steps:
1. Liquefaction of Air:
Air is compressed and cooled to its liquefaction point (approximately -194°C at atmospheric pressure). This process removes water vapor and other impurities.
2. Preliminary Distillation:
The liquid air is distilled at atmospheric pressure in a distillation column. The gases with higher boiling points, such as oxygen and nitrogen, condense at the bottom of the column, while lighter gases, such as argon and helium, remain in the vapor phase.
3. Fractional Distillation:
The condensed liquids from the preliminary distillation are further distilled in a series of fractional columns. Each column is carefully designed to maximize the separation of the gases based on their boiling points.
4. Final Separation:
Oxygen and nitrogen are separated in the main fractional column, which has a large number of trays to achieve high purity. Argon is separated in a separate column, and other gases, such as helium, neon, and xenon, are collected in smaller quantities.
Components Obtained:
- Oxygen: Approximately 21% of the volume of liquid air, used in industrial processes, medical applications, and combustion.
- Nitrogen: Approximately 78% of the volume of liquid air, used as an inert gas in industrial processes, food preservation, and fertilizers.
- Argon: Approximately 1% of the volume of liquid air, used in welding, lighting, and medical imaging.
- Helium, Neon, Xenon: Smaller quantities of these gases are also obtained, with helium being the most valuable due to its low density and inert properties.
Advantages of Fractional Distillation:
- High Purity: Produces highly pure gases with specific compositions.
- Efficient Separation: Separates gases with small differences in boiling points effectively.
- Scalable: The process can be scaled up to produce large quantities of gases for industrial applications.
Applications:
Fractional distillation of liquid air has numerous applications, including:
- Industrial Processes: Oxygen is essential for steel production, chemical manufacturing, and combustion. Nitrogen is used in refrigeration, electronics, and fertilizers.
- Medical Applications: Oxygen is used in respiratory therapy and anesthesia. Helium is used in MRI scanning and respiratory support.
- Aerospace: Liquid oxygen and nitrogen are used as propellants in rockets and satellites.
- Food Preservation: Nitrogen is used to extend the shelf life of food products by preventing oxidation.
- Lighting: Argon is used in incandescent and fluorescent light bulbs to create a stable atmosphere.