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Nov 16, 2023

An introduction on heterogeneous equilibrium using water and phenol ???? ?

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Nov 16, 2023
Heterogeneous equilibrium refers to a chemical equilibrium in which reactants and products are present in different phases. In this case, we will explore the equilibrium between water and phenol, which is a common example of a heterogeneous equilibrium.

Water (H2O) and phenol (C6H6O) can exist in two different phases: liquid and gas. At room temperature and pressure, water is typically in its liquid phase, while phenol can exist as a liquid or a gas. This difference in phases is what makes the equilibrium between water and phenol heterogeneous.

When water and phenol are in contact with each other, they can undergo a reversible reaction known as the hydration of phenol. This reaction involves the transfer of a water molecule to the phenol molecule, resulting in the formation of a hydrated phenol molecule (C6H6O·H2O).

C6H6O (phenol) + H2O (water) ⇌ C6H6O·H2O (hydrated phenol)

The equilibrium between water and phenol is influenced by factors such as temperature, pressure, and the presence of catalysts. The equilibrium constant (K) for this reaction can be determined by measuring the concentrations of the reactants and products at equilibrium.

Since water and phenol are in different phases, their concentrations are typically expressed in terms of their partial pressures (P) rather than molar concentrations (C). The equilibrium constant expression for this reaction would then be written as:

K = (P(C6H6O·H2O)) / (P(C6H6O) * P(H2O))

The value of the equilibrium constant (K) indicates the extent to which the reaction favors the formation of hydrated phenol. If K is greater than 1, the reaction favors the formation of hydrated phenol, while a value less than 1 indicates a preference for the reactants.

Understanding the concept of heterogeneous equilibrium using the example of water and phenol can provide insights into the behavior of other chemical reactions involving different phases. It also highlights the importance of considering the different phases and their respective concentrations when analyzing equilibrium systems.
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